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Measuring Carbon Nanotubes Taken Up by Plants

By Adityarup "Rup" Chakravorty
 
Carbon nanotubes are tiny. They can be a hundred thousand times smaller than the width of a human hair. But they have huge potential.
 
Products manufactured using carbon nanotubes include rebar for concrete, sporting goods, wind turbines, and lithium batteries, among others.
 
Potential uses of carbon nanotubes could extend to diverse fields, such as agriculture, biomedicine and space science.
 
But as we use more carbon nanotubes to make things, we also increase the chances that these nanotubes enter different environments and ecosystems.
Lettuce after exposure to carbon nanotubes.
Lettuce after exposure to carbon nanotubes.
 
“That makes it important to understand how carbon nanotubes behave in these environments,” says Yu Yang, a member of the Soil Science Society of America.
 
In a new study, Yang and his colleagues describe a way to measure levels of a specific kind of carbon nanotube in plant tissues. Their research was recently published in Journal of Environmental Quality.
 
Carbon nanotubes may make their way into agricultural fields and food products. There, they can pose a threat to human and environmental health.
 
“Knowing how to measure carbon nanotubes in the environment is crucial to understanding their environmental fate and effects,” says Yang.
Lettuce in hydroponic culture.
Lettuce in hydroponic culture.
 
To mimic the nanotubes in the environment, Yang and colleagues grew hydroponic lettuce in the presence of carbon nanotubes. Then they analyzed the lettuce leaves for traces of carbon nanotubes.
 
Yang found this method could detect small amounts of carbon nanotubes in the leaves, stems and roots of the lettuce plants.
 
“We have developed a method to address the challenging issue of quantifying carbon nanomaterials in the environment,” says Yang. “These findings can help guide the sustainable application of carbon nanotubes in natural environments.”
 
The challenge in measuring carbon nanotubes in the environment is that they are made of carbon. All living things on Earth – including humans and plants – have carbon as a key building block.
 
The task Yang and colleagues faced was to distinguish between carbon in living material from carbon in carbon nanotubes.
 
A single layer of carbon atoms arranged in a honeycomb pattern is called graphene. A carbon nanotube is a sheet of graphene rolled into a tiny cylinder.
 
Carbon nanotubes made of a single sheet of graphene are called single-walled nanotubes. Layering multiple tubes within others yields multi-walled carbon nanotubes.
 
Scientists can add different molecules to carbon nanotubes. Adding these molecules can change their characteristics. They might dissolve more easily in solvents, for example.
 
“Carbon nanotubes with molecules added on could be used in the fabrication of nanocomposites, biomedicine, and chemical or biological probes,” says Yang.
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Western Canadian Agriculture: Hard Times Made the World's Best Farmers

Video: Western Canadian Agriculture: Hard Times Made the World's Best Farmers

Western Canadian agriculture produced the most advanced farmers in the world not through abundance but through adversity. The crow rate fell. The wheat price went nowhere. The brown envelopes stopped.

When the subsidies disappeared, the bad farmers left and the good ones stayed. And the ones who stayed could not just grow wheat anymore. They started growing lentils and canola and peas and flax and faba beans. They built crop rotation. They got serious about agronomy because there was no government backstop. That process produced the Western Canadian agriculture Dennis Bulani describes in this clip: the most advanced, most educated farming culture in the world.

His contrast with Iowa corn and soybean farmers is sharp. At a DeKalb farmer meeting in Okoboji, Iowa, he asked what crop rotation they ran. Beans on corn stubble, corn on bean stubble. How do you fertilize? The co-op agronomist handles it. Have you considered other crops? No need. We make so much money on corn and soybeans. Western Canadian agriculture was never allowed that comfort. And now those Iowa farmers are watching soybean markets lock up with China and corn prices slide, and they do not have the agronomy knowledge or the research base to pivot. Western Canadian farmers adapted on a dime because they had done it before.

Dennis also makes the case that Western Canadian agriculture keeps adapting in real time. Low commodity prices over the past year have pushed growers to look seriously at precision spot-spray technology. He knows a neighbor who bought a sprayer with the seeing-eye system and sprayed only 80 out of 320 acres. As a chemical retailer Dennis acknowledges that will affect his sales. He supports it anyway, because if it advances Canadian agriculture and makes farmers money, that is a good outcome.

The lesson Dennis draws from the tale of two farms: continuous improvement is the only durable strategy. When canola was $22 a bushel some growers went to Arizona instead of the Crop Production Show. When the price came down those same growers came back to the research and the discipline. Products do not go on Rack Petroleum's shelves unless they pass a replicated trial first. That is what Western Canadian agriculture built through hard times: farmers who do the work whether the times demand it or not.

Dennis Bulani is CEO of Rack Petroleum and Ultimate Yield in Biggar, Saskatchewan. Dan Aberhart hosts GTF Productions, Western Canadian Agriculture's foremost live briefing platform and its foremost AI training platform for ag operators